5-Bromo-1H-pyrrolo[2,3-b]pyridine

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5-Bromo-1H-pyrrolo­[2,3-b]pyridine

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In the title compound, C(9)H(8)BrNO, the non-H-atom framework is essentially planar, with a maximum deviation of 0.087 (3) Å. In the crystal, mol-ecules are inter-connected into a three-dimensional network by C-H⋯O and N-H⋯O hydrogen bonds. In addition, C-H⋯π inter-actions and a π-π stacking inter-action, with a centroid-centroid distance of 3.5535 (19) Å, are also observed.

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The title compound, C(13)H(9)BrO, has been synthesized by the intra-molecular Friedel-Crafts reaction of 1-(1-bromo-4-naphth-yl)-3-chloro-propan-1-one. There are two approximately planar [maximum deviations of 0.8 (2) and 0.4 (2) Å in the two mol-ecules] molecules in the asymmetric unit. The dihedral angle between their mean planes is 19.72 (8)°. Weak inter-molecular C-H⋯O hydrogen bonding is p...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2013

ISSN: 1600-5368

DOI: 10.1107/s1600536813004157